The second button from the left in the toolbar is the open locale button.
You can click this to launch an open file dialog to find a stringer locale yaml file.
You can also open an existing document from the file menu, or by using the open document shortcut of Ctrl + o
on Windows and Linux or ⌘ + o
on Mac.
Be sure to save changes to your open file before opening another locale, otherwise the changes will be lost.